Desymmetrization of cyclic olefins via asymmetric Heck reaction and hydroarylation.
نویسندگان
چکیده
An asymmetric Heck reaction allows desymmetrization of substituted cyclic olefins in high dr and ee. A bisphosphine oxide is uniquely stereoselective for this purpose. Desymmetrization of bicyclic olefins via hydroarylation can also be realized in high ee.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 100 شماره
صفحات -
تاریخ انتشار 2013